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HYDRATED HCl COMPLEXES, (HCl)${_m}$(H${_2}$O)${_n}$, IN HELIUM NANODROPLETS: OH STRETCHING MODES

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/46081

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Title: HYDRATED HCl COMPLEXES, (HCl)${_m}$(H${_2}$O)${_n}$, IN HELIUM NANODROPLETS: OH STRETCHING MODES
Creators: Lee, Seung Jun; Choi, Myong Yong; Skvortsov, Dimitry; Vilesov, Andrey F.
Issue Date: 2010
Abstract: Infrared laser spectroscopy has been used to characterize the solvation of HCl with small number of water molecules in helium nanodroplets. Complexes of (HCl)${_m}$(H${_2}$O)${_n}$ with m = 1 -- 3 and n = 1 -- 3 have been identified in the free OH stretching and bonded OH spectral range of 3000 -- 3900 cm$^{-1}$. The assignment of the infrared vibrational bands of the clusters is aided by pick-up pressure dependence experiments and ab initio calculations.
URI: http://hdl.handle.net/1811/46081
Other Identifiers: 2010-FB-09
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