OSU Navigation Bar

The Ohio State University University Libraries Knowledge Bank

THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/38362

Show full item record

Files Size Format View
abstract.gif 14.61Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Ohio State talk_hot band talk2.ppt 1.374Mb Microsoft PowerPoint View/Open
Slide1.GIF 28.87Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide2.GIF 49.82Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide3.GIF 11.59Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide4.GIF 12.78Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide5.GIF 17.49Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide6.GIF 26.49Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide7.GIF 21.64Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide8.GIF 8.644Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide9.GIF 18.10Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide10.GIF 32.81Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide11.GIF 24.72Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide12.GIF 5.921Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide13.GIF 6.930Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide14.GIF 11.80Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide15.GIF 9.104Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide16.GIF 9.891Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide17.GIF 22.66Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide18.GIF 9.112Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide19.GIF 8.400Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide20.GIF 10.71Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide21.GIF 8.004Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide22.GIF 8.342Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide23.GIF 7.778Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide24.GIF 9.889Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide25.GIF 10.23Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide26.GIF 10.66Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide27.GIF 11.88Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide28.GIF 7.727Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide29.GIF 7.044Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide30.GIF 10.22Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Slide31.GIF 10.92Kb GIF image Thumbnail of THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$

Title: THE JAHN-TELLER (JT) EFFECT IN THE $\widetilde{A}$ STATE OF THE NITRATE RADICAL NO$_3$
Creators: Takematsu, Kana; Eddingsaas, Nathan; Okumura, Mitchio; Stanton, John
Issue Date: 2009
Abstract: The JT effect in the $\widetilde{A}$$^2$E$^{\prime \prime}$ of NO$_3$ is poorly understood. A preliminary spectrum of the vibronically-allowed $\widetilde{A}$$\leftarrow$$\widetilde{X}$ transition, coupled with ab initio calculations, shows moderate JT activity in the $\widetilde{A}$ state. Vibronic bands exhibit either static or dynamic JT distortions depending on the vibrational level of the upper $\widetilde{A}$ state. The picture of the $\widetilde{A}$ state is however incomplete. For example, in the E$^{\prime \prime}$$\otimes$e$^{\prime}$=a$_1$$^{\prime \prime}$$\oplus$a$_2$$^{\prime \prime}$$\oplus$e$^{\prime \prime}$ manifold, while the splitting would provide a direct measure of the JT strength, only the a$_1$$^{\prime \prime}$ levels have been observed. We have gained new insight into the $\widetilde{A}$ state by examining the hot bands of NO$_3$ which access previously unobserved dark levels of the $\widetilde{A}$ state.
URI: http://hdl.handle.net/1811/38362
Other Identifiers: 2009-WJ-11
Bookmark and Share