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ANALYSIS OF THE MAGNETIC HYPERFINE STRUCTURE IN THE $B^{3}$$\Phi_{4}-X^{3}\Phi_{4}$ BAND SYSTEM OF IRIDIUM MONOFLUORIDE, IrF

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/38209

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Title: ANALYSIS OF THE MAGNETIC HYPERFINE STRUCTURE IN THE $B^{3}$$\Phi_{4}-X^{3}\Phi_{4}$ BAND SYSTEM OF IRIDIUM MONOFLUORIDE, IrF
Creators: Wang, Hailing; Zhuang, Xiujuan; Steimle, Timothy C.; Linton, Colan
Issue Date: 2009
Abstract: Recently the New Brunswick group (accepted).} reported on the detection and analysis of the $B^{3}$$\Phi_{4}-X^{3}\Phi_{4}$ band system of IrF. The free-jet expansion conditions limited the spectral resolution to approximately 200 MHz, which was insufficient to fully resolve the $^{191}$Ir(I=3/2), $^{193}$Ir(I=3/2)and $^{19}$F(I=1/2)magnetic hyperfine splitting. Here we report on the analysis of the same band system recorded under molecular beam conditions which resulted in a resolution of 40 MHz. A simple molecular orbital correlation diagram is used to rationalize the determined parameters of IrF and the isovalent molecules RhF {\textbf{121}} 2591, 2004.} and CoF {\textbf{127}} 194308, 2007.}.
URI: http://hdl.handle.net/1811/38209
Other Identifiers: 2009-RF-04
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