OSU Navigation Bar

The Ohio State University University Libraries Knowledge Bank

The Knowledge Bank is scheduled for regular maintenance on Sunday, April 20th, 8:00 am to 12:00 pm EDT. During this time users will not be able to register, login, or submit content.

MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/38150

Show full item record

Files Size Format View
abstract.gif 21.38Kb GIF image Thumbnail of MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO
PrO.ppt 9.294Mb Microsoft PowerPoint View/Open
Slide1.GIF 95.29Kb GIF image Thumbnail of MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO
Slide2.GIF 107.2Kb GIF image Thumbnail of MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO
Slide3.GIF 129.3Kb GIF image Thumbnail of MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO
Slide4.GIF 80.12Kb GIF image Thumbnail of MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO
Slide5.GIF 84.09Kb GIF image Thumbnail of MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO
Slide6.GIF 90.83Kb GIF image Thumbnail of MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO
Slide7.GIF 98.36Kb GIF image Thumbnail of MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO
Slide8.GIF 89.64Kb GIF image Thumbnail of MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO
Slide9.GIF 77.33Kb GIF image Thumbnail of MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO
Slide10.GIF 102.2Kb GIF image Thumbnail of MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO
Slide11.GIF 105.9Kb GIF image Thumbnail of MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO
Slide12.GIF 92.92Kb GIF image Thumbnail of MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO
Slide13.GIF 88.63Kb GIF image Thumbnail of MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO
Slide14.GIF 95.31Kb GIF image Thumbnail of MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO

Title: MAGNETIC g$_e$-FACTORS AND ELECTRIC DIPOLE MOMENTS OF LANTHANIDE MONOXIDES: PrO
Creators: Wang, Hailing; Steimle, Timothy C.; Linton, Colan
Issue Date: 2009
Abstract: The very complex optical spectra of the lanthanide monoxides are caused by the insensitivity of the electronic energies to the numerous possible arrangements of the Ln$^{2+}$ electrons in the 4f and 6s orbitals. Disentangling the complex optical spectra may be aided by using simple Ligand Field Theory(LFT) to establish the global electronic structure for the low-lying electronic states. A comparison of experimentally determined permanent electric dipole moments, $\mu$$_{el}$, and magnetic dipole moments, $\mu$$_{m}$, is an effective means of sorting this myriad of states and assessing the quality of LFT and other electronic structure methodologies. Here we report on the determination of the permanent electric dipole moments, $\mu$$_{el}$, and magnetic g${_e}$-factors for the X$_{2}$($\Omega$ = 4.5) and [18.1] ($\Omega$ = 5.5) states of PrO from the analysis of the optical Stark and Zeeman spectra. The g$_{e}$-factors are compared with those computed using wavefunctions predicted from ligand field theory\underline {\textbf{131}} 301, 1988.}. The $\mu$$_{el}$ value for the X$_{2}$($\Omega$ = 4.5) state is compared to \textit {ab initio} \underline{\textbf{75}},369, 1989.}, and density functional \underline {\textbf{18}} 444, 2007.} predictions and with the experimental values of other lanthanide monoxides. A phenomenological fit of $\mu$$_{el}$ for the entire series of LnO is used to predict $\mu$$_{el}$ for the isovalent actinide monoxide series.
URI: http://hdl.handle.net/1811/38150
Other Identifiers: 2009-RF-09
Bookmark and Share