OSU Navigation Bar

The Ohio State University University Libraries Knowledge Bank

ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/33529

Show full item record

Files Size Format View
abstract.gif 18.56Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Columbus2008Talk2.ppt 25.94Mb Microsoft PowerPoint View/Open
Columbus2008Talk2.pdf 11.08Mb PDF View/Open
Slide1.GIF 43.52Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide2.GIF 71.23Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide3.GIF 75.99Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide4.GIF 51.61Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide5.GIF 68.02Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide6.GIF 71.71Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide7.GIF 70.76Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide8.GIF 63.44Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide9.GIF 36.17Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide10.GIF 86.73Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide11.GIF 11.25Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide12.GIF 83.07Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide13.GIF 13.67Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide14.GIF 54.19Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide15.GIF 56.33Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide16.GIF 45.05Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide17.GIF 76.34Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide18.GIF 71.08Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide19.GIF 63.41Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide20.GIF 40.97Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide21.GIF 42.74Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide22.GIF 72.39Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide23.GIF 66.93Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide24.GIF 75.26Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide25.GIF 111.7Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide26.GIF 78.13Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide27.GIF 66.59Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide28.GIF 84.28Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide29.GIF 34.99Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide30.GIF 166.3Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide31.GIF 123.1Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide32.GIF 41.49Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Slide33.GIF 62.41Kb GIF image Thumbnail of ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES

Title: ROVIBRONIC ENERGY TOPOGRAPHY II: MOLECULAR INTERNAL-MOMENTUM EFFECTS AND MULIT-RES RESONANCE IN HIGH SYMMETRY MOLECULES
Creators: Harter, William G.; Mitchell, Justin C.
Issue Date: 2008
Abstract: Multi-surface rotational-energy-surfaces (RES) help to unravel Coriolis effects involving molecules with internal angular momentum due to nuclear spin, hindered rotors, or rovibronic coupling}, 319 (1988).}}, 11688 (1999).}. Fine and superfine spectral structures may show markedly different sensitivity to relative strength of scalar ($B \zeta$) and tensor Coriolis coupling and to the total angular momentum quantum value $J$. Unstable saddle points are often located on axes of $C_{2}$ local symmetry. RES plots show how they are stabilized by resonant Coriolis spin or vibronic interactions. This applies to molecules of symmetry ranging from asymmetric up to octahedral or icosahedral. Spectral signatures of this includes increased clustering and species mixing. An example involving $v_{3}$ fundamentals in $XY_{6}$ molecular models shows appearance of 12-fold rovibrational cluster degeneracy. The resulting selective breakdown of Born-Oppenheimer-approximate (BOA) quantum numbers is analyzed by examining topography of multiple RES surfaces and by comparing their results to full-diagonalization eigensolutions.
URI: http://hdl.handle.net/1811/33529
Other Identifiers: 2008-RE-10
Bookmark and Share