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ELECTRONIC SPECTRA OF CALIX[n]ARENE AND ITS VAN DER WAALS CLUSTERS IN SUPERSONIC JETS

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dc.creator Ebata, T. en_US
dc.creator Nishimoto, K. en_US
dc.creator Hontama, N. en_US
dc.creator Inokuchi, Y. en_US
dc.date.accessioned 2008-07-15T13:51:18Z
dc.date.available 2008-07-15T13:51:18Z
dc.date.issued 2008 en_US
dc.identifier 2008-RC-06 en_US
dc.identifier.uri http://hdl.handle.net/1811/33502
dc.description T. Ebata, Y. Hodono, T. Ito and Y. Inokuchi, J. Chem. Phys. 126, 141101 (2007). en_US
dc.description Author Institution: Department of Chemistry, Graduate School of Science, Hiroshima University, Higashi-Hiroshima, 739-8526, Japan en_US
dc.description.abstract Electronic structure and encapsulation of neutral guest molecules have been studied for Calix[4]arene (C4A)} and Calix[5]arene (C5A) in supersonic jets. By the measurements of UV-UV hole burning and IR-UV double resonance spectra, it was found that C4A has a single isomer with C$_4$ symmetry, while C5A has at least two isomers; one isomer has C$_5$ symmetry while the other isomer has the structure in which one of the phenol is inverted. The ability of the encapsulation has been studied by using rare gas, nitrogen, and methane as guest molecules. The electronic spectra suggest that the first guest molecule is encapsulated inside the cavity while the next molecules are bound outside. en_US
dc.language.iso English en_US
dc.title ELECTRONIC SPECTRA OF CALIX[n]ARENE AND ITS VAN DER WAALS CLUSTERS IN SUPERSONIC JETS en_US
dc.type Article en_US