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THE PURE ROTATIONAL SPECTRUM OF PIVALOYL CHLORIDE, (CH$_3$)$_3$CCOCl, BETWEEN 800 MHz AND 18800 MHz

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/33371

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Title: THE PURE ROTATIONAL SPECTRUM OF PIVALOYL CHLORIDE, (CH$_3$)$_3$CCOCl, BETWEEN 800 MHz AND 18800 MHz
Creators: Grubbs, Garry S., II; Dewberry, Christopher T.; Etchision, Kerry C.; Cooke, Stephen A.; Serafin, Michel M.; Peebles, Sean A.
Issue Date: 2008
Abstract: A search accelerated correct intensity Fourier transform microwave (SACI-FTMW) spectrometer has been used to rapidly record the rotational spectrum of pivaloyl chloride between 8 and 18 GHz. A low frequency, cavity-based instrument has then been used to obtain high resolution measurements below 4 GHz. Rotational constants, centrifugal distortion constants and chlorine nuclear quadrupole coupling constants have been determined for both the $^{35}$Cl and $^{37}$Cl isotopologues. The spectrum provides no evidence concerning internal rotation in the molecule.
URI: http://hdl.handle.net/1811/33371
Other Identifiers: 2008-FC-08
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