OSU Navigation Bar

The Ohio State University University Libraries Knowledge Bank

ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/31362

Show simple item record

Files Size Format View
abstract.gif 17.45Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
2007 Benzodioxole.ppt 1.734Mb Microsoft PowerPoint View/Open
Slide1.GIF 18.92Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide2.GIF 12.58Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide3.GIF 35.18Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide4.GIF 45.66Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide5.GIF 74.89Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide6.GIF 45.10Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide7.GIF 48.29Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide8.GIF 52.81Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide9.GIF 10.81Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide10.GIF 12.58Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide11.GIF 34.44Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide12.GIF 55.23Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide13.GIF 12.00Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide14.GIF 14.88Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide15.GIF 7.119Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide16.GIF 14.22Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide17.GIF 14.70Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide18.GIF 13.17Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide19.GIF 8.818Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide20.GIF 15.33Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide21.GIF 25.87Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide22.GIF 10.87Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide23.GIF 13.54Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide24.GIF 1.023Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide25.GIF 36.10Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide26.GIF 47.50Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide27.GIF 13.75Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide28.GIF 37.24Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide29.GIF 35.02Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide30.GIF 74.38Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide31.GIF 8.391Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide32.GIF 7.853Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE
Slide33.GIF 6.592Kb GIF image Thumbnail of ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE

dc.creator Thomas, Jessica A. en_US
dc.creator Alvarez-Valtierra, Leonardo en_US
dc.creator Pratt, D. W. en_US
dc.date.accessioned 2008-01-12T13:50:19Z
dc.date.available 2008-01-12T13:50:19Z
dc.date.issued 2007 en_US
dc.identifier 2007-FD-04 en_US
dc.identifier.uri http://hdl.handle.net/1811/31362
dc.description Author Institution: Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260 en_US
dc.description.abstract The anomeric effect, observed in molecules containing -O-CH$_{2}$-O- groups, occurs when there is an overlap of an oxygen atom lone pair orbital with an antibonding molecular orbital from the adjacent C-O bond, and leads to a distortion of the molecule along some out-of-plane coordinate. An example of a molecule containing this sequence is 1,3-benzodioxole. In this molecule, the anomeric effect leads to a puckering of the five-membered ring, breaking conjugative links between the two rings. Rotationally resolved spectra of the origins and several vibronic bands of 1,3-benzodioxole will be compared to an analog, 2,3-dihydrobenzofuran (coumaran), which contains only one oxygen atom. Each of these molecules has two rings that are able to bend with respect to one another along the shared bond. In addition, each contains a nonconjugated ring that has the ability to pucker. The rotationally resolved spectra will be used to determine whether the bending or puckering modes predominate in each molecule. en_US
dc.language.iso English en_US
dc.title ANALYSIS OF THE ANOMERIC EFFECT USING ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF 1,3-BENZODIOXOLE IN THE GAS PHASE en_US
dc.type article en_US