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PUMP-PROBE PHOTOIONIZATION AND MASS SPECTROSCOPY OF PENTAMETHYLCYCLOPENTADIENE

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/31234

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Title: PUMP-PROBE PHOTOIONIZATION AND MASS SPECTROSCOPY OF PENTAMETHYLCYCLOPENTADIENE
Creators: Rudakov, F. M.; Weber, Peter M.
Issue Date: 2007
Abstract: The ultrafast radiationless decays in cyclic dienes normally proceed through conical intersections of potential energy surfaces. Time-resolved experiments on pentamethylcyclopentadiene were performed by exciting the first excited state with femtosecond pulses at 267 nm. Photoionization with a time-delayed probe pulse yields delay-time dependent mass and photoelectron spectra that reveal the ultrafast character of the curve crossing dynamics.
URI: http://hdl.handle.net/1811/31234
Other Identifiers: 2007-RC-07
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