THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/30981

Show full item record

Files Size Format View
abstract.gif 20.70Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
RE07_Petkie.ppt 1.880Mb Microsoft PowerPoint View/Open
Slide1.GIF 54.85Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide2.GIF 60.83Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide3.GIF 79.52Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide4.GIF 38.35Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide5.GIF 12.39Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide6.GIF 45.54Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide7.GIF 9.892Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide8.GIF 9.667Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide9.GIF 10.48Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide10.GIF 10.80Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide11.GIF 10.88Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide12.GIF 9.318Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide13.GIF 11.70Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide14.GIF 7.942Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide15.GIF 10.74Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide16.GIF 8.383Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide17.GIF 7.827Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide18.GIF 10.98Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide19.GIF 9.623Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide20.GIF 9.966Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Slide21.GIF 41.63Kb GIF image Thumbnail of THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$

Title: THE ROTATIONAL SPECTRUM OF $H^{15}NO_{3}$: ALL STATES BELOW 1000 $cm^{-1}$
Creators: Petkie, Douglas T.; Kipling, Mark; Jones, Ashely; Helminger, Paul; Medvedev, Ivan R.; Maeda, A.; Drouin, Brian J.; Miller, Charles E.
Issue Date: 2006
Publisher: Ohio State University
Abstract: The rotational spectrum of $H^{15}NO_{3}$ was recorded using isotope enriched samples at Ohio State University with the FASSST spectrometer and at the Jet Propulsion Laboratory with the cascaded frequency multiplication spectrometer. The OSU system used a heated cell over the frequency range of 118-370 GHz while the JPL room temperature measurements included the frequency ranges of 74-109, 400-410, 639-656, and 800-850 GHz. Transitions in the ground and six lowest vibrational states, $6^{1}$, $7^{1}$, $8^{1}$, $9^{1}$, and the $5^{1}/9^{2}$ dyad, have been assigned and fit using Watson-type Hamiltonians. The $9^{1}$ and $9^{2}$ states require torsional parameters to account for the observed torsional splitting of $\sim$2.4 MHz and $\sim$70 MHz, respectively. Fermi and Coriolis interactions were included to accurately describe the strong interactions in the $5^{1}/9^{2}$ dyad and to account for an observed torsional splitting of $\sim$15 MHz induced onto the $5^{1}$ state. The analysis of each state will be presented along with a discussion of the spectroscopic constants.
Description: Author Institution: Department of Physics, Wright State University, Dayton OH 45435; Department of Physics, University of South Alabama, Mobile, AL 36688; Department of Physics, The Ohio State University, Columbus, OH 43210; Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109-8099
URI: http://hdl.handle.net/1811/30981
Other Identifiers: 2006-RE-07
Bookmark and Share