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HIGH-RESOLUTION SPECTROSCOPY ON DOUBLY DEUTERATED AMMONIA UP TO 2.6 THz

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/30976

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dc.creator Endres, Christian P. en_US
dc.creator Müller, Holger S. P. en_US
dc.creator Giesen, Thomas F. en_US
dc.creator Schlemmer, Stephan en_US
dc.creator Lewen, Frank en_US
dc.creator Paveliev, Dimitri G. en_US
dc.date.accessioned 2008-01-12T13:15:35Z
dc.date.available 2008-01-12T13:15:35Z
dc.date.issued 2006 en_US
dc.identifier 2006-RE-02 en_US
dc.identifier.uri http://hdl.handle.net/1811/30976
dc.description Author Institution: I. Physikalisches Institut, Universitat zu Koln, Zulpicher Str.77, 50937 Koln, Germany; Department of Radiophysics, N. Novgorod State University, Russia en_US
dc.description.abstract High accuracy spectra of ND$_2$H up to frequencies of 2.6 THz have been recorded by the use of frequency multiplication techniques in combination with phase locked, high power backward wave oscillators (BWO). For the first time we used novel superlattice (SL) devices as key-element for the generation of higher order harmonics in spectroscopic applications. Odd multiplication factors up to 11 have been achieved and used to measure ground state transitions of the pure rotation and inversion-rotation spectra of ND$_2$H in the frequency range between 0.08 and 2.58 THz with accuracies of several kilohertz. Energy levels up to quantum numbers $J=18$ and $K_a=9$ have been accessed. A greatly extended experimental dataset was obtained with significantly improved accuracies. Besides a technical description of the spectrometer setup, a short presentation and analysis of the spectra will be given in the talk. The improved molecular parameters, derived in the analysis, allowed to generate predictions that can be regarded as a reliable basis for future astronomical high resolution observations throughout the microwave to terahertz regions. These predictions will be available in the Cologne Database for Molecular Spectroscopy (www.cdms.de). en_US
dc.language.iso English en_US
dc.title HIGH-RESOLUTION SPECTROSCOPY ON DOUBLY DEUTERATED AMMONIA UP TO 2.6 THz en_US
dc.type article en_US