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ROTATIONAL SPECTRA AND STRUCTURAL PARAMETERS OF BIS($\eta$$_5$-CYCLOPENTADIENYL)TUNGSTEN DIHYDRIDE

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/30858

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Title: ROTATIONAL SPECTRA AND STRUCTURAL PARAMETERS OF BIS($\eta$$_5$-CYCLOPENTADIENYL)TUNGSTEN DIHYDRIDE
Creators: Tackett, Brandon S.; Karunatilaka, Chandana; Daly, Adam; Kukolich, Stephen G.
Issue Date: 2006
Abstract: Microwave spectroscopy measurements and density functional theory calculations are reported for the bis($\eta$$_5$-cyclopentadienyl)tungsten dihyride complex and its deuterium substituted isotopomers. Rotational transition frequencies were measured in the 4-18 GHz range using a Flygare-Balle-type pulsed beam spectrometer. (C$_5$H$_5$)$_2$WH$_2$ is a near-prolate asymmetric top with preliminary rotational constants of A= 2062, B= 855, and C= 844 MHz for the main $^{184}$W isotopomer. Measurements were made to obtain the M-H bond and H-H distances to determine if this a dihydrogen complex.
URI: http://hdl.handle.net/1811/30858
Other Identifiers: 2006-FE-09
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