OSU Navigation Bar

The Ohio State University University Libraries Knowledge Bank

THE $v_{t}=3$ STATE OF METHANOL

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/30830

Show full item record

Files Size Format View
abstract.gif 14.17Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
vt3meohCol06.ppt 811.5Kb Microsoft PowerPoint View/Open
Slide1.GIF 11.25Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
Slide2.GIF 29.02Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
Slide3.GIF 12.87Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
Slide4.GIF 51.46Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
Slide5.GIF 9.161Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
Slide6.GIF 8.712Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
Slide7.GIF 12.22Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
Slide8.GIF 12.01Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
Slide9.GIF 10.50Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
Slide10.GIF 13.84Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
Slide11.GIF 10.64Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
Slide12.GIF 13.64Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
Slide13.GIF 18.15Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
Slide14.GIF 67.91Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
Slide15.GIF 53.66Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL
Slide16.GIF 13.44Kb GIF image Thumbnail of THE $v_{t}=3$ STATE OF METHANOL

Title: THE $v_{t}=3$ STATE OF METHANOL
Creators: Pearson, J. C.; Drouin, Brian J.; Braakman, Rogier; Blake, Geoffrey A.
Issue Date: 2006
Abstract: The rotational spectrum of methanol is characterized by an asymmetric top overall rotation coupled with an intermediate barrier three fold hindered rotation. The spectrum progresses from a torsionally modified asymmetric top in the $v_{t}=0$ state to a rotationally modified torsion by the $v_{t}=2$ state. The $v_{t}=3$ state lies well above the torsional barrier and in close proximity to the CO stretch vibration. The $v_{t}=3$ microwave spectrum has been assigned up to $J=34$ in over 1 THz of frequency measured spectra. In spite of the success in assigning the a-type R-branches the b-type spectra is surprisingly weak suggesting that the torsion significantly modifies the intensities of the few $K$ levels in close enough proximity to have transitions below 2.5 THz.
URI: http://hdl.handle.net/1811/30830
Other Identifiers: 2006-FC-05
Bookmark and Share