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THE SPECTROSCOPY AND STRUCTURE OF THIOPHOSGENE (Cl$_2$CS) IN ITS SINGLET A$_2$ STATE: A HIGH RESOLUTION STUDY OF THE ROTATIONAL STRUCTURE OF THE n $\rightarrow \pi^*$ TRANSITION

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/30582

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dc.creator Fujiwara, T. en_US
dc.creator Lim, E. C. en_US
dc.creator Judge, R. H. en_US
dc.creator Kodet, John en_US
dc.creator Moule, D. C. en_US
dc.date.accessioned 2008-01-11T21:54:49Z
dc.date.available 2008-01-11T21:54:49Z
dc.date.issued 2005 en_US
dc.identifier 2005-TG-03 en_US
dc.identifier.uri http://hdl.handle.net/1811/30582
dc.description Author Institution: Department of Chemistry and Centre for Laser and Optical Spectroscopy, The University of Akron, Akron, OH 44325-3601 ; Department of Chemistry, University of Wisconsin-Parkside, Kenosha, WI 53141-2000 ; Department of Chemistry, Brock University, St. Catharines, ON L2S 3A1 en_US
dc.description.abstract BG test - The results of our recent line-by-line rotational analysis of the ring dye laser LIF jet spectrum of the $^1$A$_2 \leftarrow ^1$A$_1$ (n $\rightarrow \pi^*$) rovibronic transition of thiophosgene (Cl$_2$CS) will be presented. A total of four bands have been analyzed. An interesting feature of the spectrum is the axis-switching that occurs in the excited state of the $^{35}$Cl$_2$CS and $^{35}$Cl$^{37}$ClCS isotopomers. The excited state geometry has been determined from a fit to the least-squares determined rotational constants. The molecule is approximately $24^{irc}$ out-of-plane which is lower than that determined from earlier Franck-Condon type analyses of the vibrational structure. We attribut the discrepancy to the one-dimensional nature of the model calculations used in these previous studies. en_US
dc.language.iso English en_US
dc.title THE SPECTROSCOPY AND STRUCTURE OF THIOPHOSGENE (Cl$_2$CS) IN ITS SINGLET A$_2$ STATE: A HIGH RESOLUTION STUDY OF THE ROTATIONAL STRUCTURE OF THE n $\rightarrow \pi^*$ TRANSITION en_US
dc.type article en_US