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LASER MAGNETIC RESONANCE SPECTRUM OF THE $\nu _{2}$ BAND OF $AsH_{2}^{\ast}$

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/29226

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dc.creator Muenchausen, R. E. en_US
dc.creator McCoy, W. J. en_US
dc.creator Hills, G. W. en_US
dc.date.accessioned 2007-08-31T14:13:15Z
dc.date.available 2007-08-31T14:13:15Z
dc.date.issued 1982 en_US
dc.identifier 1982-RC-5 en_US
dc.identifier.uri http://hdl.handle.net/1811/29226
dc.description $^{\ast}$Research supported by the ACS-PRF en_US
dc.description.abstract The $\nu_{2}$ bending mode of the $AsH_{2}$ radical in the $\tilde{X}^{2}B_{1}$ state has been investigated using $CO_{2}$ laser magnetic resonance spectroscopy. A large number of resonances have been observed in the $920-1070 cm^{-1}$ region. Many resonances show the characteristic quarters of resolved $^{75}As (T=3/2)$ hyperline structure. The $AsH_{2}$ radical was produced in a discharge flow system by adding to arsine $(AsH_{3})$ the products of a microwave discharge of $H_{2}$ in Ar. The current evidence for the active species as $AsH_{2}$ is mainly chemical. The results of the spectrum assignment and parameter determination, currently underway, should confirm the identity. en_US
dc.format.extent 56270 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title LASER MAGNETIC RESONANCE SPECTRUM OF THE $\nu _{2}$ BAND OF $AsH_{2}^{\ast}$ en_US
dc.type article en_US