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ROTATIONALLY RESOLVED LASER EXCITATION SPECTRA OF $Pb_{2}, Sn_{2}$, and $Se_{2}$

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/28965

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Title: ROTATIONALLY RESOLVED LASER EXCITATION SPECTRA OF $Pb_{2}, Sn_{2}$, and $Se_{2}$
Creators: Heaven, M. C.; Bondybey, V. E.; Miller, Terry A.; English, J. H.
Issue Date: 1982
Abstract: The technique of pulsed laser vaporization, as described in a previous abstract, has been used to produce samples of $Pb_{2}, Sn_{2}$, and $Se_{2}$ in the gas phase. The molecules were cooled to near 77k by entraining them in a flow of the which had been pre-cooled by liquid $N_{2}$. Laser excitation spectra were recorded with near Doppler limited resolution, providing the first rotationally resolved spectra for $Pb_{2}$ and $Sn_{2}$. Two electronic transitions of $^{208}Pb_{2}$ were observed, the $F({O_{u}}^{+}) - X({O_{g}}^{+})$ and $C({O_{u}}^{+}) - X({O_{g}^{+})$ systems. Several vibronic bands have been analyzed for both system. When $^{116}Sn$ is vaporized, two electronic transitions are present in the laser excitation spectra. In this case the transitions are partially overlaped, resulting in a complex vibronic structure. Rotational analysis is in progress for bands of both systems. For $Se_{2}$ we report the observations and analysis of the new $A^{3}\pi_{u} - X^{3}{\Sigma_{g}}^{-}$ transition.
URI: http://hdl.handle.net/1811/28965
Other Identifiers: 1982-WF-4
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