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THE STRUCTURE OF CYCLOPENTADIENYL TUNGSTEN TRICARBONYL HYDRIDE $COMPLEX^{a}$

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/21393

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Title: THE STRUCTURE OF CYCLOPENTADIENYL TUNGSTEN TRICARBONYL HYDRIDE $COMPLEX^{a}$
Creators: Tanjaroon, Chakree; Keck, Kristen; Karunatilaka, Chandana; Kukolich, Stephen G.
Issue Date: 2004
Abstract: We report the structural parameters for the cyclopentadienyl tungsten tricarbonyl hydride complex. Tungsten and molybedum carbonyl mono-hydride complexes have recently been explored as possible agents for hydrogenation catalysts. We have now obtained spectra for five unique 13C and a D-isotopomers using a pulsed-beam FT spectrometer system. This is the first measurement of the structure for a tungsten mono-hydride complex. The present structural data obtained from the Kraitchman and structure fits analyses are in good agreement with results obtained from DFT calculations. [FIGURE]
URI: http://hdl.handle.net/1811/21393
Other Identifiers: 2004-TC-09
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