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AIR-BROADENING PARAMETERS IN THE $\nu_{3}$ BAND OF $^{14}N^{16}O_{2}$ USING A MULTISPECTRUM FITTING TECHNIQUE

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/21255

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Title: AIR-BROADENING PARAMETERS IN THE $\nu_{3}$ BAND OF $^{14}N^{16}O_{2}$ USING A MULTISPECTRUM FITTING TECHNIQUE
Creators: Benner, D. Chris; Devi, V. Malathy; Blake, Thomas A.; Brown, L. R.; Toth, R. A.; Smith, M. A. H.
Issue Date: 2004
Abstract: Air-broadened line widths, pressure-induced shift coefficients and their temperature dependences were retrieved for over 700 transitions in the $\nu_{3}$ band of $^{14}N^{16}O_{2}$ at $6 \mu m$. In addition, precise line center positions and relative intensities were also determined. The results were obtained by fitting simultaneously 27 spectra recorded at high resolution ($0.002 cm^{-1}$ to $0.006 cm^{-1}$) with two different Fourier transform spectrometers and gas sample temperatures ranging from 206 K to 298 K. It was necessary to modify the multispectrum fitting $software^{a}$ to accommodate constraints on the retrieved parameters of closely-spaced spin-split doublets in order to successfully determine broadening and shift parameters for the components of these doublets. The variations of the line broadening and shift parameters with the quantum numbers were investigated. Subsets of the observed line widths were reproduced to within 3% using an empirical smoothing function.$^{b}$
URI: http://hdl.handle.net/1811/21255
Other Identifiers: 2004-RB-06
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