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COMPLETE VIBRATIONAL CHARACTERIZATION OF THE $B{^{1}}\Sigma^{+}$ STATE THROUGH DOUBLE RESONANCE SPECTROSCOPY.

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/21087

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dc.creator Viteri, C. Ricardo en_US
dc.creator Clark, Jason en_US
dc.creator Gilkison, Andrew T. en_US
dc.creator Grant, Edward R. en_US
dc.date.accessioned 2006-06-15T20:43:53Z
dc.date.available 2006-06-15T20:43:53Z
dc.date.issued 2003 en_US
dc.identifier 2003-WF-10 en_US
dc.identifier.uri http://hdl.handle.net/1811/21087
dc.description Author Institution: Department of Chemistry, Purdue University en_US
dc.description.abstract We have performed new experiments that characterize the outer well of the double minimum B1S+ electronic state of BH in terms of its rotational vibrational level structure. Rovibrational states of $BH B{^{1}}\Sigma^{+}$ are observed as ionization detected absorption features in double resonance scans via the $v=3$ level of the $A{^{1}}\Pi$ state. Experimental observations conform with high level ab initio calculations that determine the position and energy of the internal barrier. This work represents the first observation of the vibrational level structure of the outer well. en_US
dc.format.extent 131233 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title COMPLETE VIBRATIONAL CHARACTERIZATION OF THE $B{^{1}}\Sigma^{+}$ STATE THROUGH DOUBLE RESONANCE SPECTROSCOPY. en_US
dc.type article en_US