THE CHLORINE NUCLEAR QUADRUPOLE COUPLING CONSTANT IN HSiCl

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Title: THE CHLORINE NUCLEAR QUADRUPOLE COUPLING CONSTANT IN HSiCl
Creators: Lin, Wei; Novick, Stewart E.; Fukushima, Masaru; Jäger, Wolfgang
Issue Date: 2002
Publisher: Ohio State University
Abstract: HSiCl was produced by a pulsed discharge of free expansions of $(CH_{3})_{3}SiCl$ or $HSiCl_{3}$ diluted in a rare gas carrier. The $1_{01} - 0_{00}$ microwave transitions in $H^{28}Si^{35}Cl$, $H^{28}Si^{37}Cl$, $H^{29}Si^{35}Cl$, $H^{30}Si^{35}Cl$ were measured at 14 - 15 GHz by FTMW spectroscopy. The effective rotational constants were obtained and the chlorine nuclear quadrupole coupling constants of the four isotopomers were determined. These hyperfine constants will be discussed and compared with those of related chlorosilylenes and chlorosilanes.
Description: $^{a}$Permanent address: Faculty of Information Sciences, Hiroshima City University, Asa-Minami, Hiroshima 731-3194,Japan ${^{b}}$Support by Hiroshima City University President-Designated Grant for Long-Term Research Abroad for Young Researchers is gratefully acknowledged.
Author Institution: Department of Chemistry, Wesleyan University; Department of Chemistry, University of Alberta
URI: http://hdl.handle.net/1811/20657
Other Identifiers: 2002-TJ-09
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