# $C_{2v}$-TOP INTERNAL ROTATION IN THE HIGH-RESOLUTION UV SPECTRA OF WEAKLY BOUND COMPLEXES: II. $APPLICATIONS.^{a}$

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 Title: $C_{2v}$-TOP INTERNAL ROTATION IN THE HIGH-RESOLUTION UV SPECTRA OF WEAKLY BOUND COMPLEXES: II. $APPLICATIONS.^{a}$ Creators: Schafer, Martin; Pratt, D. W. Issue Date: 2001 Publisher: Ohio State University Abstract: The model of a $C_{2v}$ top --- $C_{s}$ frame internal rotation discussed in Part I has been used in the analysis of rotationally resolved $S_{1} \leftarrow S_{0}$ fluorescence excitation spectra of three different complexes; aniline$-N_{2}$, para-difluorobenzene$-N_{2}$, and benzonitrile$-H_{2}O$. The results of the internal rotation analysis as well as the structure determination will be presented and the limits of the applied model will be discussed. Description: $^{a}$Work supported by the Swiss National Science Foundation and NSF. Author Institution: Department of Chemistry, University of Pittsburgh; Department of Chemistry, University of Pittsburgh URI: http://hdl.handle.net/1811/20142 Other Identifiers: 2001-RF-02