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THE ROTATIONAL SPECTRUM OF CIS- AND TRANS-FORMIC ACID, REVISITED

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/20083

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dc.creator Winnewisser, B. P. en_US
dc.creator Winnewisser, M. en_US
dc.creator Stein, Monika en_US
dc.creator Birk, M. en_US
dc.creator Wagner, G. en_US
dc.creator Winnewisser, G. en_US
dc.creator Yamada, Koichi M. T. en_US
dc.creator Belov, S. P. en_US
dc.creator Baskakov, Oleg I. en_US
dc.date.accessioned 2006-06-15T20:10:05Z
dc.date.available 2006-06-15T20:10:05Z
dc.date.issued 2001 en_US
dc.identifier 2001-RA-02 en_US
dc.identifier.uri http://hdl.handle.net/1811/20083
dc.description $^{a}$Present address: Department of Physics, The Ohio State University, Columbus, Ohio 43210, $^{b}$Present address: Department of Physics, The Ohio State University, Columbus, Ohio 43210 en_US
dc.description Author Institution: Physikalisch-Chemisches Institut der Justus-Liebig-Universit\""at; DLR Oberpfaffenhofen; Universit\""at zu K\""oln; I. Physikalisches Institut, Universit\""at zu K\""oln; I. Physikalisches Institut, Kharkov State University en_US
dc.description.abstract The initial experimental confirmation of the existence of the cis rotamer of formic acid, HCOOH, was based on a small number of pure rotational transitions in the microwave region [W. H. Hocking, Z Naturforsch. 31a, 1113-1121 (1976)]. Since then, there have been no further report of the observation of spectral features attributable to this species. In order to extend the study of the spectrum of cis-HCOOH we have recorded the far infrared spectrum of HCOOH from 30 to $100 cm^{-1}$ (Oberpfaffenhofen). This spectrum has now been supplemented by millimeter wave measurements (Kharkov) and submillimeter wave measurements (K\""oln), so that a very extensive set of data is now available for both rotamers. The analysis of the spectrum (Giessen, Kharkov)has now yielded a more complete set of ground state constants for each rotamer than was previously available, providing in particular a sound basis for the search for infrared transitions of cis-HCOOH. en_US
dc.format.extent 285788 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title THE ROTATIONAL SPECTRUM OF CIS- AND TRANS-FORMIC ACID, REVISITED en_US
dc.type article en_US