Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/19989
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dc.creator | Ganpathi, Naresh Patwari | en_US |
dc.creator | Ebata, Takayuki | en_US |
dc.creator | Mikami, N. | en_US |
dc.date.accessioned | 2006-06-15T20:06:45Z | |
dc.date.available | 2006-06-15T20:06:45Z | |
dc.date.issued | 2001 | en_US |
dc.identifier | 2001-FA-02 | en_US |
dc.identifier.uri | http://hdl.handle.net/1811/19989 | |
dc.description | Author Institution: Graduate School of Science, Tohoku University; Department of Chemistry, Graduate School of Science, Tohoku University | en_US |
dc.description.abstract | It is well known that a hydrogen atom attached to an electronegative element, such as oxygen or nitrogen or halogen, acquires a partial positive charge, while a hydrogen atom bonded to an electropositive element, such as boron or metal, acquires a partial negative charge. It is therefore possible for these oppositely charged hydrogen atoms to interact favorably. Thus the dihydrogen bond is an electrostatic / dipolar interaction of the type E-H...H-X (where E and X are electropositive and electronegative atoms, respectively, with respect to hydrogen). Though the existence of dihydrogen bond is known for more than a decade, almost all the evidence is crystallographic and theoretical. Recently we have observed dihydrogen bonded complexes between phenol and borane-amine adducts (borane-dimethylamine and borane-trimethylamine) in the gas phase. The characterization of these complexes using infrared spectroscopy together with the ab-initio calculations will be discussed. | en_US |
dc.format.extent | 207166 bytes | |
dc.format.mimetype | image/jpeg | |
dc.language.iso | English | en_US |
dc.publisher | Ohio State University | en_US |
dc.title | GAS PHASE DIHYDROGEN BONDED COMPLEXES OF PHENOL AND BORANE-AMINE ADDUCTS | en_US |
dc.type | article | en_US |
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