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GAS PHASE DIHYDROGEN BONDED COMPLEXES OF PHENOL AND BORANE-AMINE ADDUCTS

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/19989

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dc.creator Ganpathi, Naresh Patwari en_US
dc.creator Ebata, Takayuki en_US
dc.creator Mikami, N. en_US
dc.date.accessioned 2006-06-15T20:06:45Z
dc.date.available 2006-06-15T20:06:45Z
dc.date.issued 2001 en_US
dc.identifier 2001-FA-02 en_US
dc.identifier.uri http://hdl.handle.net/1811/19989
dc.description Author Institution: Graduate School of Science, Tohoku University; Department of Chemistry, Graduate School of Science, Tohoku University en_US
dc.description.abstract It is well known that a hydrogen atom attached to an electronegative element, such as oxygen or nitrogen or halogen, acquires a partial positive charge, while a hydrogen atom bonded to an electropositive element, such as boron or metal, acquires a partial negative charge. It is therefore possible for these oppositely charged hydrogen atoms to interact favorably. Thus the dihydrogen bond is an electrostatic / dipolar interaction of the type E-H...H-X (where E and X are electropositive and electronegative atoms, respectively, with respect to hydrogen). Though the existence of dihydrogen bond is known for more than a decade, almost all the evidence is crystallographic and theoretical. Recently we have observed dihydrogen bonded complexes between phenol and borane-amine adducts (borane-dimethylamine and borane-trimethylamine) in the gas phase. The characterization of these complexes using infrared spectroscopy together with the ab-initio calculations will be discussed. en_US
dc.format.extent 207166 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title GAS PHASE DIHYDROGEN BONDED COMPLEXES OF PHENOL AND BORANE-AMINE ADDUCTS en_US
dc.type article en_US