FOURIER TRANSFORM MICROWAVE SPECTROSCOPIC INVESTIGATION OF CARBONYLSULFIDE LOOSELY BOUND TO TWO HELIUM ATOMS

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Title: FOURIER TRANSFORM MICROWAVE SPECTROSCOPIC INVESTIGATION OF CARBONYLSULFIDE LOOSELY BOUND TO TWO HELIUM ATOMS
Creators: Xu, Yunjie; Jäger, Wolfgang
Issue Date: 2000
Publisher: Ohio State University
Abstract: Rotational spectra of the van der Waals complex of carbonylsulfide (OCS) loosely bound to two helium atoms were investigated using a cavity Fourier transform microwave (MW) spectrometer and a MW-MW double resonance spectrometer. Seven isotopomers, namely those with $^{16}O^{12}C^{32}S, ^{16}O^{12}C^{34}S, ^{16}O^{13}C^{32}S, ^{16}O^{12}C^{33}S, ^{18}O^{13}C^{32}S$, and $^{17}O^{13}C^{32}S$ were studied. Nuclear hyperfine structures due to the quadrupolar $^{33}S$ and $^{17}O$ nuclei were observed and analyzed. The interesting dynamics with this cluster will be presented and discussed.
Description: Author Institution: Department of Chemistry, University of Alberta
URI: http://hdl.handle.net/1811/19935
Other Identifiers: 2000-WE-13
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