HIGH RESOLUTION SPECTRUM OF THE 1.2-DIMETHOXYBENZENE/$D_{2} O$ $COMPLEX^{a}$

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 Title: HIGH RESOLUTION SPECTRUM OF THE 1.2-DIMETHOXYBENZENE/$D_{2} O$ $COMPLEX^{a}$ Creators: Yi, John T.; Pratt, D. W. Issue Date: 2000 Publisher: Ohio State University Abstract: The rotationally resolved $S_{1} \leftarrow S_{0}$ electronic spectrum of the 1,2-dimethoxybenzene/$D_{2}O$ complex has been analyzed. The $D_{2}O$ complex appears $126 cm^{-1}$ to the blue of the bare molecule origin. The complex spectrum exhibits two subbands separated by 45 MHz. These spectra have an intensity ratio of 2 to 1, with the stronger band shifted to lower frequency. Possible motions of the water molecule that are suggested by these data will be discussed. Description: $^{a}$work supported by NSF Author Institution: Department of Chemistry, University of Pittsburgh URI: http://hdl.handle.net/1811/19727 Other Identifiers: 2000-RB-05