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FAR INFRARED LMR SPECTROSCOPIC MEASUREMENTS OF THE QUASI-LINEAR MOLECULE DCCN

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/19632

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Title: FAR INFRARED LMR SPECTROSCOPIC MEASUREMENTS OF THE QUASI-LINEAR MOLECULE DCCN
Creators: Jones, W. E.; Sun, F.; Curl, R. F., Jr.; Allen, M. D.; Evenson, K. M.; Brown, J. M.
Issue Date: 2000
Abstract: FIR laser magnetic resonance spectra of the quasilinear free radical DCCN, produced by fluorine atom abstraction of deuterium from deuterated acetonitrile $(CD_{3}CN)$, has been measured at laser wavelengths between 46 and $136 \mu m$. The spectra have been analyzed using a triplet asymmetric rotor Hamiltonian. Included in the fitting data set are the millimeter wave $data ^{a}$ for the $\nu_{5}=0$ and 1 levels. This analysis has allowed the determination of some Zeeman constants and the refinement of the molecular constants of DCCN.
URI: http://hdl.handle.net/1811/19632
Other Identifiers: 2000-FC-03
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