# INTEGRATED INTENSITIES OF OH VIBRATIONAL OVERTONES IN ALCOHOLS

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 Title: INTEGRATED INTENSITIES OF OH VIBRATIONAL OVERTONES IN ALCOHOLS Creators: Phillips, J. A.; Orlando, J. J.; Tyndall, G.; Vaida, V. Issue Date: 1999 Publisher: Ohio State University Abstract: Intensities for several OH vibrational overtone bands have been measured for vapor phase methanol, ethanol, and isopropanol. The trends in the intensities as a function of excitation level have been modeled by two empirical approaches, yielding intensity predictions for the higher overtone transitions, up to $7\nu(OH)$. These methods were also applied to recent $HNO_{3}$ overtone measurements, resulting in new intensity predictions for higher, photochemically-active overtone bands, which are compared with theoretical estimates. Description: Author Institution: Department of Chemistry, University of Wisconsin-Eau Claire; Atmospheric Chemistry Division, National Center for Atmospheric Research; Department of Chemistry and Biochemistry, University of Colorado URI: http://hdl.handle.net/1811/19579 Other Identifiers: 1999-WH-13