THE INFRARED SPECTRA OF $SO_{2}^{-}$ AND $(SO_{2})_{2}^{-}$ ISOLATED IN SOLID NEON

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1999

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Ohio State University

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Studies of the infrared absorptions shown by $SO_{2}$ samples codeposited in a large excess of neon at 5 K with a beam of neon atoms excited in a microwave discharge will be presented. Analysis of the data results in the identification of $SO_{2}$ and of $(SO_{2})_{2}^{-}$. The previously reported infrared spectral assignment for $SO_{2}^{-}$ is revised, and information is obtained regarding the structure of $(SO_{2})_{2}^{-}$.

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Author Institution: Optical Technology Division, National Institute of Standards and Technology

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