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HIGH RESOLUTION INFRARED EMISSION SPECTROSCOPY OF DICHLOROBORANE $BHCl_{2}$

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/18930

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dc.creator Hirao, T. en_US
dc.creator Colarusso, Pina en_US
dc.creator Bernath, P. F. en_US
dc.date.accessioned 2006-06-15T19:04:16Z
dc.date.available 2006-06-15T19:04:16Z
dc.date.issued 1998 en_US
dc.identifier 1998-RF-17 en_US
dc.identifier.uri http://hdl.handle.net/1811/18930
dc.description Author Institution: Department of Chemistry, University of Waterloo en_US
dc.description.abstract The absorption spectrum of dichloroborane $BHCl_{2}$ was accidentally recorded during Fourier transform emission measurements of HBO. Gaseous dichloroborane was generated by the reaction of amorphous boron powder with $CaCl_{2}$ at 1400 C. The bands centred near 2617, 1089 and $892 cm^{-1}$ were assigned as the $\nu_{1}$ (B-H stretch), the $\nu_{5}$ (HBCl bend), and the $\nu_{6} (BCl_{2}$ antisymmetric stretch) fundamental modes, respectively. Modular constants were determined from rotational analyses of these bands. This is a first analysis of the rotational structure of the $\nu_{5}$ and $\nu_{6}$ modes. en_US
dc.format.extent 65620 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title HIGH RESOLUTION INFRARED EMISSION SPECTROSCOPY OF DICHLOROBORANE $BHCl_{2}$ en_US
dc.type article en_US