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LASER INDUCED FLUORESCENCE SPECTROSCOPY OF $Rg \cdot SH$ COMPLEXES $(Rg = Ne, Ar$ and Kr)

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/18734

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Title: LASER INDUCED FLUORESCENCE SPECTROSCOPY OF $Rg \cdot SH$ COMPLEXES $(Rg = Ne, Ar$ and Kr)
Creators: Yang, Min-Chieh; Salzberg, Aldo P.; Carter, Christopher C.; Miller, Terry A.
Issue Date: 1993
Abstract: For the first time, the jet-cooled, laser induced fluorescence spectra of $\tilde{A} - \tilde{X}$ transitions of $Rg \cdot SH$ complexes were observed. In $Ne \cdot SH$, six bands were recorded and we believe most are transitions to the internal rotational levels of the $\tilde{A}$ state. In $Ar\cdot SH$, five $v_{5}$ bands ($v_{5}$, denotes the RgSH stretch) and other vibronic bands believed involving combination of $v_{5}$ and internal rotor motion were observed. In $Kr\cdot SH$, at least $6 v_{2}$ bands and several vibronic bands were found. In addition, we have observed transitions in the excitation spectra belonging to $Rg_{n}\cdot SH (n \geq 2)$ species for $Rg = Ne, Ar$ and Kr. The details of the analysis will be presented.
URI: http://hdl.handle.net/1811/18734
Other Identifiers: 1993-WH-8
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