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THE MICROWAVE SPECTRUM OF THE METHYLCYCLOPROPANE-HCl COMPLEX

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/18614

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dc.creator Forest, Susan E. en_US
dc.creator Andrews, Anne M. en_US
dc.creator Kuczkowski, R. L. en_US
dc.date.accessioned 2006-06-15T18:54:26Z
dc.date.available 2006-06-15T18:54:26Z
dc.date.issued 1993 en_US
dc.identifier 1993-TC-6 en_US
dc.identifier.uri http://hdl.handle.net/1811/18614
dc.description Author Institution: Department of Chemistry, University of Michigan; Molecular Physics Division, National Institute of Standards and Technology en_US
dc.description.abstract The microwave spectrum of the methylcyclopropane(MCP)-HCl complex has been observed using a pulsed nozzle, molecular beam Fourier transform microwave spectrometer. Transitions were assigned with the aid of the quadrupole hyperfine structure from the chlorine nucleus. The rotational constants of the $C_{4}H_{7}-H^{35}Cl$ species are $A = 6408.1(2) MHz, B = 1410.486(1) MHz, C = 1224.155(1) MHz$. In addition to this species, the spectra of the MCP $H^{37}Cl$ and $MCP-DCl$ isotopomers have also been studied. The data is consistent with the HCl attached to the C-C bond of the MCP ring that is adjacent to the methyl substituted carbon. en_US
dc.format.extent 70478 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title THE MICROWAVE SPECTRUM OF THE METHYLCYCLOPROPANE-HCl COMPLEX en_US
dc.type article en_US