HIGH RESOLUTION SPECTROSCOPY OF RARE GAS-SH COMPLEXES
Loading...
Date
1993
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
Rotationally resolved, laser-induced fluorescence spectra of $Rg\cdot SH$ complexes have been recorded for the first time. These complexes were produced by the photolysis of a mixture of 1\% $H_{2}S$ in He with a small amount of the appropriate inert gas. The molecule was jet cooled and probed with a pulse amplified cw ring dye laser with a resolution of 300MHz in the UV. We observe both fine and hyperfine structure in $Ar \cdot SH$ analogous to $Ar \cdot SH$. We have also confirmed that previously unidentified bands of $Ar \cdot SH^{1}$ are in fact combination bands of both the van der Waals stretch and bend. Spectra of all previously observed pure van der Waals stretch bands of $Ar \cdot SH$ have now been recorded and we will discuss the analysis of these bands. Presently work is also in progress on the $Ar \cdot SH$ and the $Kr \cdot SH$ complexes.
Description
$^{1.}$ M. C. Yang, A. P. Salzberg, B. -C. Chang, C. C. Carter, and T. A. Miller, J. Chem. Phys. 98, 4301 (1993).
Author Institution: Laser Spectroscopy Facility, Department of Chemistry, The Ohio State University
Author Institution: Laser Spectroscopy Facility, Department of Chemistry, The Ohio State University