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FTIR STUDY OF TRICARBON HYDRIDE RADICALS $(C_{3}H_{n}, n \leq 5)$ TRAPPED IN AN ARGON MATRIX AT 10 $K^{2}$

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/18360

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Title: FTIR STUDY OF TRICARBON HYDRIDE RADICALS $(C_{3}H_{n}, n \leq 5)$ TRAPPED IN AN ARGON MATRIX AT 10 $K^{2}$
Creators: Huang, Jiunwoei; Graham, W. R. M.
Issue Date: 1990
Abstract: An FTIR study of the products of the vacuum uv photolysis of $CH_{3}CCH$, methylacetylene and its partially and fully deuterated istopomers has revealed new information on the vibrational spectra of a variety of tricarbon hydride radicals, $C_{3}H_{n} <n \leq 5$). New vibrations for $C_{2}H$, propynylidyne; $C_{3}H_{2}$, cis- and trans-propenediylidene, and $C_{3}H_{3}$, cyclopropenyl are proposed. Also observed are the cyclopropenylidene, vinylidenecarbene, and propargylene isomers of $C_{3}H_{2}$, and the $C_{3}H_{3}$, allyl radical. On the basis of isotopic data previous vibrational assignments are confirmed, and in some cases, revisions are suggested
URI: http://hdl.handle.net/1811/18360
Other Identifiers: 1990-WE-9
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