# Knowledge Bank

## University Libraries and the Office of the Chief Information Officer

The Knowledge Bank is scheduled for regular maintenance on Sunday, April 20th, 8:00 am to 12:00 pm EDT. During this time users will not be able to register, login, or submit content.

# An IAM Theory for Internal Rotation in Completely Asymmetric Molecules. Application to the Analysis of the Microwave Spectra of $CH_{2}DOH$ and $CHD_{2}OH$.

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/17950

Files Size Format View
1989-TC-06.jpg 58.29Kb JPEG image

 Title: An IAM Theory for Internal Rotation in Completely Asymmetric Molecules. Application to the Analysis of the Microwave Spectra of $CH_{2}DOH$ and $CHD_{2}OH$. Creators: Liu, Mujian; Quade, C. R. Issue Date: 1989 Abstract: An IAM theory has been developed for application in the spectral analysis of $CH_{2}DOH^{1}$ and $CHD_{2}OH{^{2}}$. Torsion-rotation term values are calculated with first principles from the molecular structure in $a_{3}$single degree of internal freedom model. A modified V and G structure gives the best fit to the data, even improving upon the phenomonological approach reported with the $spectra.^{1,2}$ However, it is clear from the spectral fit that vibration-rotation-internal rotation interactions are also important. URI: http://hdl.handle.net/1811/17950 Other Identifiers: 1989-TC-6