OSU Navigation Bar

The Ohio State University University Libraries Knowledge Bank

The Knowledge Bank is scheduled for regular maintenance on Sunday, April 20th, 8:00 am to 12:00 pm EDT. During this time users will not be able to register, login, or submit content.

ROTATIONAL STRUCTURE IN THE SINGLET-TRIPLET EXCITATION SPECTRA OF POLYATOMIC $MOLECULES.^{1}$

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/17875

Show simple item record

Files Size Format View
1989-RD-05.jpg 60.14Kb JPEG image Thumbnail of ROTATIONAL STRUCTURE IN THE SINGLET-TRIPLET EXCITATION SPECTRA OF POLYATOMIC $MOLECULES.^{1}$

dc.creator Spangler, L. H. en_US
dc.creator Holtzclaw, K. W. en_US
dc.creator Pratt, D. W. en_US
dc.date.accessioned 2006-06-15T18:20:40Z
dc.date.available 2006-06-15T18:20:40Z
dc.date.issued 1989 en_US
dc.identifier 1989-RD-5 en_US
dc.identifier.uri http://hdl.handle.net/1811/17875
dc.description $^{1}$ Work supported by NSF. $^{2}$ J. T. Hougen. Can. J. Phys. 42. 433 (1964). en_US
dc.description Author Institution: Department of Chemistry, Montana State University.; Physical Sciences. Inc., Research Park. Andover. MA 01810.; Department of Chemistry., University of Pittsburgh, en_US
dc.description.abstract We have observed rotational structure in the beam- and jet-cooled $T_{1}\leftarrow S_{0}$ phosphorescence excitation spectra of several molecules, including glyoxal, pyrazine and benzaldehyde. Each observed resolved or partially-resolved contour exhibits a significantly different shape, a shape that is also different from the corresponding bands in the $S_{1}\leftarrow S_{0}$ spectrum. We will discuss the origin of these differences in this talk. Our approach is that of $Hougen_{2}$ which emphasizes the strong connection between the radiative properties of the triplet state in the gas and condensed phase, in a natural way. en_US
dc.format.extent 61589 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title ROTATIONAL STRUCTURE IN THE SINGLET-TRIPLET EXCITATION SPECTRA OF POLYATOMIC $MOLECULES.^{1}$ en_US
dc.type article en_US