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LASER EXCITED SPECTRA OF THE SINGLET MOLECULAR OXYGEN-IODINE REACTION AND POPULATIONS OF INTERMEDIATE STATES

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dc.creator Crozet, P. en_US
dc.creator Bacis, R. en_US
dc.creator Bouvier, A. en_US
dc.creator Bouvier, A. J. en_US
dc.creator Churassy, S. en_US
dc.date.accessioned 2006-06-15T18:14:02Z
dc.date.available 2006-06-15T18:14:02Z
dc.date.issued 1988 en_US
dc.identifier 1988-TC-6 en_US
dc.identifier.uri http://hdl.handle.net/1811/17670
dc.description Author Institution: Laboratolre de Spectrometrie lonique et Moleculatre en_US
dc.description.abstract As reported in the previous paper the mechanism of dissociation of $1_{2}$ by $O_{2}$ Is poorly known. It is a multi-step process. In order to find the Intermediate states of l2 involved we have systematically explored excitation spectra of the flame with a dye laser pumped by a copper vapour laser. Moreover some high resolution spectra have been obtained in the 810 -830 nm range with a styryl dye pumped by an $Ar^{4}$ laser. From inversion of the excitation spectra we have found that high vibrational levels of the $l_{2}$ ground state until $v \sim 45$ are involved. These vibrtional populations vary with the region of the flame explored. With a frequency doubled dye laser we succeeded to detect a relatively high population of the $A^{\prime}2u$ state through $A^{\prime}2u$ state through $A2u \rightarrow D2g$ excitation. Unfortunately the D2g state is spectroscoplcally too poorly known to obtain relable inversion of the spectra. en_US
dc.format.extent 145586 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title LASER EXCITED SPECTRA OF THE SINGLET MOLECULAR OXYGEN-IODINE REACTION AND POPULATIONS OF INTERMEDIATE STATES en_US
dc.type article en_US