FOURIER TRANSFORM SPECTROSCOPY OF $^{7}Li_{2}$: THE $1^{3}\Sigma^{+}_{g}-1^{3}\Sigma^{+}_{u}$ TRANSITION

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dc.creator Bacis, R. en_US
dc.creator Martin, F. en_US
dc.creator Linton, C. en_US
dc.creator Bujin, Guo en_US
dc.creator Cheng, C. H. en_US
dc.creator Stad, E. en_US 2006-06-15T18:08:36Z 2006-06-15T18:08:36Z 1988 en_US
dc.identifier 1988-MF-16 en_US
dc.description Author Institution: Laboratoire de Spectrometrie Ionique et Moleculaire, Universite Claude Bernard-Lyon I; Physics Department, University of New Brunswick en_US
dc.description.abstract Fluorescence resulting from excitation of $^{3}Li_{2}$ by the 476.5 nm line of an Argon ion laser has been detected at very high resolution using a Fourier Transform spectrometer at Orsay. A very rich, complex spectrum is obtained in the 8000-10000 cm-1 region. By comparing results of a preliminary rotational analysis with ab-initio calculations, the spectrum has been assigned to the $1^{3}\Sigma^{+}_{g}-1^{3}\Sigma^{+}_{u}$ transition, and is the first triplet system of $Li_{2}$ to be observed at high resolution. The results of a global fit to the 31 analyzed bands will be presented and rotational constants, dissociation energies, potential curves and Franck-Condon Factors will be discussed and compared with ab-initio calculations. en_US
dc.format.extent 124596 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.publisher Ohio State University en_US
dc.title FOURIER TRANSFORM SPECTROSCOPY OF $^{7}Li_{2}$: THE $1^{3}\Sigma^{+}_{g}-1^{3}\Sigma^{+}_{u}$ TRANSITION en_US
dc.type article en_US