THE MICROWAVE SPECTRUM OF KR-PF3

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Title: THE MICROWAVE SPECTRUM OF KR-PF3
Creators: Hillig, K. W., II; Labarge, M. S.; Bittner, E.; Bohn, Robert K.; Taylor, R. C.; Kuczkowski, R. L.
Issue Date: 1988
Publisher: Ohio State University
Abstract: The rotational spectrum of the weak complex between krypton and phosphorus trifluoride has been observed using a Fourier transform microwave spectrometer with a pulsed supersonic nozzle molecular beam source. The complex is an asymmetric top. The distance $r_{cm}$ between the krypton atom and the center of mass of the $PF_{3}$ molecule is 4.072 A and the angle between the rcm vector and the $C_{3}$ axis of the $PF_{3}$ is 68.25*. The $P_{4}$ centrifugal distortion constants, the dipole moment and the 83Kr quadrupole coupling constants have also been determined. The results will be compared to those of Ar-PF3.
Description: Author Institution: Department of Chemistry, University of Michigan; Department of Chemistry, University of Connecticut
URI: http://hdl.handle.net/1811/17451
Other Identifiers: 1988-FB-11
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