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VIBRATIONAL AND ELECTRONIC SPECTRA OF THE PRODUCTS OF THE H + HCN REACTION TRAPPED IN SOLID ARGON$^{1}$

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/17334

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Title: VIBRATIONAL AND ELECTRONIC SPECTRA OF THE PRODUCTS OF THE H + HCN REACTION TRAPPED IN SOLID ARGON$^{1}$
Creators: Jacox, Marilyn E.
Issue Date: 1987
Abstract: When H atoms produced by photolysis or by a microwave discharge react with HCN and the products are trapped in solid argon at 14 K, several infrared absorptions attributable to species of formula $CH2N$ appear, as do prominent absorptions of HNC. Filtered mercury-arc photolysis studies have established two different photodecomposition thresholds for the $CH_{2}N$ species, and isotopic substituion studies are consistent with the identification of $H_{2}CN$ and with the presence of at least one of the HCNH rotamers. Ultraviolet absorption studies have confirmed the previous assigment of several diffuse bands to $H_{2}CN$ and have extended the band system for this species to higher frequencies.
URI: http://hdl.handle.net/1811/17334
Other Identifiers: 1987-TD-2
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