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VELOCITY MODULATION LASER SPECTROSCOPY OF NEGATIVE IONS: THE INFRARED SPECTRUM OF HYDROSULFIDE ($SH^{-}$)

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/17196

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dc.creator Gruebele, M. en_US
dc.creator Polak, M. en_US
dc.creator Saykally, R. J. en_US
dc.date.accessioned 2006-06-15T17:59:12Z
dc.date.available 2006-06-15T17:59:12Z
dc.date.issued 1987 en_US
dc.identifier 1987-ME-8 en_US
dc.identifier.uri http://hdl.handle.net/1811/17196
dc.description Author Institution: Department of Chemistry, University of California en_US
dc.description.abstract Twenty-five transitions in the $v=0+1$ and $v=1+2$ bands of $^{32}SH^{-}$, as well as in the fundamentals of $^{33}SH^{-}$ and $^{34}SH^{-}$ have been measured with a diode laser by the velocity modulation technique. The data set was fit to an effective Hamiltonian through sextie terms to determine equilibrium molecular parameters. Comparison with the neutral SH radical shows a strong similarity in the anion and neutral molecular constants, as in the case of $OH^{-}$. The agreement of experiment with ab initio calculations is found to be quite good. en_US
dc.format.extent 89259 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title VELOCITY MODULATION LASER SPECTROSCOPY OF NEGATIVE IONS: THE INFRARED SPECTRUM OF HYDROSULFIDE ($SH^{-}$) en_US
dc.type article en_US