# VELOCITY MODULATION LASER SPECTROSCOPY OF NEGATIVE IONS: THE INFRARED SPECTRUM OF HYDROSULFIDE ($SH^{-}$)

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/17196

Files Size Format View
1987-ME-08.jpg 87.16Kb JPEG image

 dc.creator Gruebele, M. en_US dc.creator Polak, M. en_US dc.creator Saykally, R. J. en_US dc.date.accessioned 2006-06-15T17:59:12Z dc.date.available 2006-06-15T17:59:12Z dc.date.issued 1987 en_US dc.identifier 1987-ME-8 en_US dc.identifier.uri http://hdl.handle.net/1811/17196 dc.description Author Institution: Department of Chemistry, University of California en_US dc.description.abstract Twenty-five transitions in the $v=0+1$ and $v=1+2$ bands of $^{32}SH^{-}$, as well as in the fundamentals of $^{33}SH^{-}$ and $^{34}SH^{-}$ have been measured with a diode laser by the velocity modulation technique. The data set was fit to an effective Hamiltonian through sextie terms to determine equilibrium molecular parameters. Comparison with the neutral SH radical shows a strong similarity in the anion and neutral molecular constants, as in the case of $OH^{-}$. The agreement of experiment with ab initio calculations is found to be quite good. en_US dc.format.extent 89259 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title VELOCITY MODULATION LASER SPECTROSCOPY OF NEGATIVE IONS: THE INFRARED SPECTRUM OF HYDROSULFIDE ($SH^{-}$) en_US dc.type article en_US