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APPLICATION OF VIBRONIC COUPLING FORMALISM TO THE DETERMINATION OF VIBRATIONAL CIRCULAR DICHROISM INTENSITIES

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/16813

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dc.creator Freedman, T. B. en_US
dc.creator Nafie, L. A. en_US
dc.date.accessioned 2006-06-15T17:46:53Z
dc.date.available 2006-06-15T17:46:53Z
dc.date.issued 1984 en_US
dc.identifier 1984-TF-5 en_US
dc.identifier.uri http://hdl.handle.net/1811/16813
dc.description Author Institution: Department of Chemistry, Syracuse University en_US
dc.description.abstract The vibronic coupling expression for magnetic dipole interaction presented in the previous paper have been used to interpret the VCD spectra of molecules containing intramolecular rings closed by hydrogen bonding or metal ion coordination. The VCD intensities for a number of vibrational modes in these molecules cannot be adequately explained using VCD theories which employ approximate position dependent magnetic moment operators. For alanine and cobalt complexes of alanine and ethylene diamine, the lowest energy electronic transitions involve charge transfer between the hydrogen bonded or coordinated nuclei. The vibronic coupling terms due to these electronic transitions will be shown to generate contributions to the vibrational magnetic dipole transition moment of the proper sign. en_US
dc.format.extent 382995 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title APPLICATION OF VIBRONIC COUPLING FORMALISM TO THE DETERMINATION OF VIBRATIONAL CIRCULAR DICHROISM INTENSITIES en_US
dc.type article en_US