# VIBRATIONAL SPECTRA AND STRUCTURE OF $P_{2}H_{4}$ AND $P_{2}D_{4}$

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 Title: VIBRATIONAL SPECTRA AND STRUCTURE OF $P_{2}H_{4}$ AND $P_{2}D_{4}$ Creators: Wurrey, C. J.; Durig, J. R.; Odom, J. D.; Carreira, L. A. Issue Date: 1974 Publisher: Ohio State University Abstract: The infrared and Raman spectra of solid and gaseous $P_{2}H_{4}$ and $P_{2}D_{4}$ have been obtained. From these spectra it is concluded that biphosphine exists in the gauche $(C_{2})$ conformation in both solid and fluid phases. Assignments of the normal modes have been made and a normal coordinate analysis of biphosphine has been performed. Description: Present address of L. A. Carreira: Department of Chemistry, The University o f Georgia, Athens, Georgia. Author Institution: Department of Chemistry, University of South Carolina; Department of Chemistry, The University of Georgia URI: http://hdl.handle.net/1811/16493 Other Identifiers: 1974-TH-11