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MICROWAVE SPECTRUM OF TRANS-BUTADIENE MONOXIDE

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/16273

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dc.creator Ikeda, Tatsuya en_US
dc.creator Sastry, K. V. L. N. en_US
dc.creator Curl, R. F., Jr. en_US
dc.date.accessioned 2006-06-15T17:10:46Z
dc.date.available 2006-06-15T17:10:46Z
dc.date.issued 1974 en_US
dc.identifier 1974-MF-11 en_US
dc.identifier.uri http://hdl.handle.net/1811/16273
dc.description Author Institution: Department of Chemistry, Rice University en_US
dc.description.abstract Th emicrowave spectrum of butadiene monoxide has been studied in the region 26.5 - 40.0 GHz. About 200 transitions of the types$^{(a)}$R, $^{(b)} Q$ $^{(b)}$R, $^{(b)}$P, $^{(c)}$Q, and $^{(c)} R$ have been assigned up to $J = 35$. From these the rotational constants and the centrifugal distortion constants (4th and 6th order) were determined. The rotational constants are (in MHz); $A = 17367.28$, $B = 3128.22$, $C = 3043.69$. Stark effect measurements gave $\mu_{a} = 0.99D$, $\mu_{b} = 1.58D$, $\mu_{c}=0.73D$, $\mu = 2.00D$. The rotational constants and the components of the dipole moment clearly indicate that the assigned conformer is the trans form, and this seems to be the predominant species at dry ice temperature. en_US
dc.format.extent 144590 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title MICROWAVE SPECTRUM OF TRANS-BUTADIENE MONOXIDE en_US
dc.type article en_US