MATRIX ISOLATED VIBRATIONAL SPECTRA OF SOME UNSTABLE SULFUR OXIDES

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/16003

Show full item record

Files Size Format View
1973-H-01.jpg 106.1Kb JPEG image Thumbnail of MATRIX ISOLATED VIBRATIONAL SPECTRA OF SOME UNSTABLE SULFUR OXIDES

Title: MATRIX ISOLATED VIBRATIONAL SPECTRA OF SOME UNSTABLE SULFUR OXIDES
Creators: Hopkins, Alfred G.; Brown, Chris W.
Issue Date: 1973
Publisher: Ohio State University
Abstract: Mixtures of sulfur dioxide, oxygen, and argon have been subjected to an electrodeless discharge and the gaseous products frozen onto an appropriate substrate maintained at $20^{\circ} K$ . Infrared and laser Raman spectra of the matrix isolated products have been used to identify several unstable sulfur oxides. Identification of new species was confirmed by temperature cycling and isotopic substitution. Possible reaction mechanisms will also be discussed.
Description: Author Institution: Department of Chemistry, University of Rhode Island
URI: http://hdl.handle.net/1811/16003
Other Identifiers: 1973-H-01
Bookmark and Share