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THE $\bar{A}{^{2}}A^{\prime} - \bar{X}{^{2}}A^{\prime\prime}$ SYSTEM OF HNF.

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/15836

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Title: THE $\bar{A}{^{2}}A^{\prime} - \bar{X}{^{2}}A^{\prime\prime}$ SYSTEM OF HNF.
Creators: Woodman, C. M.
Issue Date: 1969
Abstract: The absorption spectrum in the region $3800-5000\AA$ obtained in the flash photolysis of $HNF_{2}$ has been photographed at high resolution. The conclusions of the earlier $workers^{1}$ are confirmed, namely that it is due to HNF, which is bent in both ground and excited states. The band system consists of a single progression in the bending vibration $v_{2}$, and there are prominent ``axis-switching'' effects due to the large change in bond angle. The $\rho$-type doubling is interpreted in terms of interaction between ground and excited states, which correlate with the two (Renner) components of a linear $^{2}II$ state. The $v_{2}{^{\prime}} = 1$ state shows evidence of ``second-order rotational resonance'' with the $v_{3}{^{\prime}} = 1$ state.
URI: http://hdl.handle.net/1811/15836
Other Identifiers: 1969-S-9
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