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EVIDENCE FOR PSEUDOROTATION IN SIX-MEMBERED RINGS

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/15419

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Title: EVIDENCE FOR PSEUDOROTATION IN SIX-MEMBERED RINGS
Creators: Pickett, H. M.; Strauss, Herbert L.
Issue Date: 1968
Abstract: The infrared spectrum of p-dioxane, m-dioxane, s-trioxane, tetrahydropyran, and cyclohexane have been reexamined and partially reassigned in the region below $800 cm^{-1}$. In p-dioxane, the spectrum below $270 cm^{-1}$ at 3 meter path lengths and 35 torr exhibits several series of very temperature dependent, low intensity lines. Evidence that these lines arise from pseudorotation in the boat form of p-dioxane will be presented.
URI: http://hdl.handle.net/1811/15419
Other Identifiers: 1968-C-12
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