OSU Navigation Bar

The Ohio State University University Libraries Knowledge Bank

EPR SPECTRA OF $N^{15} O^{17}$ AND $N^{15}O^{18}$.

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/15201

Show full item record

Files Size Format View
1967-D-05.jpg 140.6Kb JPEG image Thumbnail of EPR SPECTRA OF $N^{15} O^{17}$ AND $N^{15}O^{18}$.

Title: EPR SPECTRA OF $N^{15} O^{17}$ AND $N^{15}O^{18}$.
Creators: Mills, James; Baird, James C.
Issue Date: 1967
Abstract: The paramagnetic resonance spectra of $N^{15}O^{17}(^{2}II_{3/2})$ and $N^{15}O^{18}(^{2}II_{3/2})$ have been observed at 9325 MHz. The resonant magnetic fields for the hyperfine component of the Zeeman transitions were measured with a relative uncertainty of 10 ppm or less, and the hyperfine splittings for $N^{15}$ and $O^{17}$ were determined. Lin and Mizushima's theoretical expression describing the nitric oxide $spectrum^{1}$ has been revised for the cases of the isotope-substituted species; the $O^{17}$ hyperfine interactions were included to second order and the latest value of the spin-orbit coupling $constant^{2}$ was used. The observed spectra were fitted semi-empirically to the resulting expressions. Magnetic hyperfine coupling parameters for oxygen in nitric oxide $(^{2}II_{3/2})$ have been computed using the 23-dimensional SCF CI wave function of $Yamazaki, et al.^{3}$.
URI: http://hdl.handle.net/1811/15201
Other Identifiers: 1967-D-5
Bookmark and Share