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THE MICROWAVE SPECTRUM OF PIVALALDEHYDE.

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/15142

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dc.creator Ronn, A. M. en_US
dc.creator Woods, R. C. en_US
dc.date.accessioned 2006-06-15T16:35:02Z
dc.date.available 2006-06-15T16:35:02Z
dc.date.issued 1966 en_US
dc.identifier 1966-V-9 en_US
dc.identifier.uri http://hdl.handle.net/1811/15142
dc.description This research was supported in part by a Contract extended to Harvard University by the Office of Naval Research, Nonr-1866(14). R. C. Woods, III is a NIH Predoctoral Fellow. en_US
dc.description Author Institution: Department of Chemistry, Harvard University en_US
dc.description.abstract The microwave spectrum of pivalaldehyde, $(CH_{3})_{3}CCHO_{1}$ has been investigated in the 9-40 Gc region. The ground state, first and second excited states of the tertiary butyl torsion and the first excited torsional state of each of the three methyl groups have been assigned. The barrier to internal rotation of the tertiary butyl top has been calculated from the splittings of the first excited state to be 1186 cal/mole, from the splittings of the second excited state to be 1170 cal/mole and from the intensity of the first excited state relative to the ground state to be 1100 cal/mole. The excited states of the methyl torsions show no splittings but the relative intensities yield barrier estimates of 2720 cal/mole, 3690 cal/mole and 3890 cal/mole, if one assumes that the three tops are independent. The dipole moment components were computed from Stark effect measurements to be $\mu_{a} = 2.56 D$ and $\mu_{b} = 0.76D$. en_US
dc.format.extent 141854 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title THE MICROWAVE SPECTRUM OF PIVALALDEHYDE. en_US
dc.type article en_US