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THE PURE ROTATIONAL SPECTRUM OF NITRIC OXIDE

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/14975

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Title: THE PURE ROTATIONAL SPECTRUM OF NITRIC OXIDE
Creators: Hall, Richard T.; Dowling, Jerome M.
Issue Date: 1966
Abstract: The pure rotational spectrum of nitric oxide was measured under high resolution $(\sim0.06 cm^{-1})$ using a lamellar grating $interferometer^{1}$ over the frequency range $18-94 cm^{-1}$. The values of the effective rotational constants, $B_{0}, D_{0}$, and $H_{0}$, were determined by least squares analyses; the values of the effective rotational constants. $B_{0}$, are in close agreement with microwave $values.^{2,3}$ The constants reproduce the observed spectrum to an average deviation of approximately $\pm 0.0012 cm^{-1}$. The unperturbed ground state constants are also given. The spin-orbit coupling constant $A_{0}$, is discussed.
URI: http://hdl.handle.net/1811/14975
Other Identifiers: 1966-C-1
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