MICROWAVE SPECTRUM OF DIMETHYLAMINE

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Title: MICROWAVE SPECTRUM OF DIMETHYLAMINE
Creators: Laurie, Victor W.; Wollrab, James E.
Issue Date: 1966
Publisher: Ohio State University
Abstract: Internal rotation, inversion and nuclear quadrupole effects were observed in the ground and excited torsional states of twelve isotopic species of dimethylamine. From the b- and c-type inversion-rotation transitions the structural parameters were calculated. The inversion doubling is a strong function of the torsional quantum numbers while the quadrupole coupling constants are unchanged. Internal rotation quartets have been resolved in the excited torsional states leading to a barrier of 3.2 kcal.
Description: Author Institution: Chemistry Department, Stanford University Stanford, California, 94305; Research Division Electro-Optics Laboratory, McDonnell Aircraft Corporation
URI: http://hdl.handle.net/1811/14961
Other Identifiers: 1966-AA-6
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